Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

Examination of the aqueous electrochemistry of a Co(II) complex bearing a pentadentate ligand suggests that the catalytic current corresponding to water oxidation is molecular in origin, and does not emanate exclusively from Co-oxide phases formed in situ.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (15), p.2107-2109
Hauptverfasser: Wasylenko, Derek J, Palmer, Ryan D, Schott, Eduardo, Berlinguette, Curtis P
Format: Artikel
Sprache:eng
Schlagworte:
Bearing
Cobalt
Emission
Interrogation
Ligands
Origins
Oxidation
Phases
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Zusammenfassung:Examination of the aqueous electrochemistry of a Co(II) complex bearing a pentadentate ligand suggests that the catalytic current corresponding to water oxidation is molecular in origin, and does not emanate exclusively from Co-oxide phases formed in situ.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc16674g