Palladium-catalyzed hydroacyloxylation of ynamides

Palladium-catalyzed hydroacyloxylation of ynamides

In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide α-acyloxyenamides.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-02, Vol.48 (10), p.1505-1507
Hauptverfasser: Smith, Donna L, Goundry, William R F, Lam, Hon Wai
Format: Artikel
Sprache:eng
Schlagworte:
Acetates - chemistry
Amides - chemical synthesis
Amides - chemistry
Carboxylic acids
Catalysis
Molecular Structure
Organometallic Compounds - chemistry
Palladium - chemistry
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Beschreibung
Zusammenfassung:In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide α-acyloxyenamides.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc13595c