Chemically Controlled Bending of Compositionally Anisotropic Microcylinders

Chemically Controlled Bending of Compositionally Anisotropic Microcylinders

The bends: Surface modification of multi‐compartmental microcylinders by spatio‐selective click chemistry and subsequent surface‐initiated atom‐transfer radical polymerization (ATRP) yield novel amphiphilic microcylinders (see scheme). Depending on the aspect ratio of the microcylinders, they can be...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-01, Vol.51 (3), p.660-665
Hauptverfasser: Saha, Sampa, Copic, Davor, Bhaskar, Srijanani, Clay, Nicholas, Donini, Alessandro, Hart, A. John, Lahann, Joerg
Format: Artikel
Sprache:eng
Schlagworte:
anisotropic materials
Anisotropy
bent molecules
Click Chemistry
microcylinders
Polymerization
Surface-Active Agents - chemistry
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Beschreibung
Zusammenfassung:The bends: Surface modification of multi‐compartmental microcylinders by spatio‐selective click chemistry and subsequent surface‐initiated atom‐transfer radical polymerization (ATRP) yield novel amphiphilic microcylinders (see scheme). Depending on the aspect ratio of the microcylinders, they can be bent or coiled.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201105387