High CO2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers

Successful incorporation of triptycene into benzimidazole-linked polymers leads to the highest CO(2) uptake (5.12 mmol g(-1), 273 K and 1 bar) by porous organic polymers and results in high CO(2)/N(2) (63) and CO(2)/CH(4) (8.4) selectivities.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (8), p.1141-1143
Hauptverfasser: Rabbani, Mohammad Gulam, Reich, Thomas E, Kassab, Refaie M, Jackson, Karl T, El-Kaderi, Hani M
Format: Artikel
Sprache:eng
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Zusammenfassung:Successful incorporation of triptycene into benzimidazole-linked polymers leads to the highest CO(2) uptake (5.12 mmol g(-1), 273 K and 1 bar) by porous organic polymers and results in high CO(2)/N(2) (63) and CO(2)/CH(4) (8.4) selectivities.
ISSN:1364-548X
DOI:10.1039/c2cc16986j