Fabrication and electrical properties of barium strontium titanate thick films by modified sol–gel method

A modified sol–gel method has been developed to prepare for the barium strontium titanate (Ba 0.6 Sr 0.4 TiO 3 , BST) thick films. The films were deposited on either Pd–Ag electroded alumina substrates (Pd–Ag/Al 2 O 3 ) or silver electroded alumina (Ag/Al 2 O 3 ) substrates by spin coating technique...

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Veröffentlicht in:Journal of electroceramics 2008-12, Vol.21 (1-4), p.503-507
Hauptverfasser: Zhang, Hongfang, Zhang, Liangying, Yao, Xi
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description A modified sol–gel method has been developed to prepare for the barium strontium titanate (Ba 0.6 Sr 0.4 TiO 3 , BST) thick films. The films were deposited on either Pd–Ag electroded alumina substrates (Pd–Ag/Al 2 O 3 ) or silver electroded alumina (Ag/Al 2 O 3 ) substrates by spin coating technique or screen printing technique. The thickness of the film was in the range of 2–10 μm. The key point of the process is to disperse fine-grained BST ceramic powders prepared by high energy ball mill into BST sol solution to form a slurry for spin coating and screen printing. In order to enhance the stability of the slurry and to avoid crack formation of the thick film, organic macromolecular poly-vinylpyrrolidone (PVP) was added to the sol solution. The structure and surface morphology of the films were studied by X-ray diffraction and Scanning Electron Microscope (SEM) techniques. It is revealed that the thick films exhibit pure perovskite phase and are crack-free, dense and homogeneous. The dielectric constant and loss tangent of the thick films are about 1200 and 0.01, at 10 °C and 1 KHz, respectively.
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Glasses ; Ceramic industries ; Ceramics ; Characterization and Evaluation of Materials ; Chemical industry and chemicals ; Chemistry and Materials Science ; Composites ; Cross-disciplinary physics: materials science; rheology ; Crystallography and Scattering Methods ; Electrochemistry ; Electrotechnical and electronic ceramics ; Exact sciences and technology ; Glass ; Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids) ; Materials Science ; Methods of deposition of films and coatings; film growth and epitaxy ; Natural Materials ; Optical and Electronic Materials ; Palladium ; Physics ; Scanning electron microscopy ; Screen printing ; Silver ; Sol gel process ; Spin coating ; Technical ceramics ; Thick films</subject><ispartof>Journal of electroceramics, 2008-12, Vol.21 (1-4), p.503-507</ispartof><rights>Springer Science+Business Media, LLC 2007</rights><rights>2009 INIST-CNRS</rights><rights>Springer Science+Business Media, LLC 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-3748f04dd0cd8e74263d7b28785dca96729f9f4fff94d81115ec49789b1205e63</citedby><cites>FETCH-LOGICAL-c408t-3748f04dd0cd8e74263d7b28785dca96729f9f4fff94d81115ec49789b1205e63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10832-007-9229-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10832-007-9229-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>309,310,314,777,781,786,787,23911,23912,25121,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=21061937$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Hongfang</creatorcontrib><creatorcontrib>Zhang, Liangying</creatorcontrib><creatorcontrib>Yao, Xi</creatorcontrib><title>Fabrication and electrical properties of barium strontium titanate thick films by modified sol–gel method</title><title>Journal of electroceramics</title><addtitle>J Electroceram</addtitle><description>A modified sol–gel method has been developed to prepare for the barium strontium titanate (Ba 0.6 Sr 0.4 TiO 3 , BST) thick films. The films were deposited on either Pd–Ag electroded alumina substrates (Pd–Ag/Al 2 O 3 ) or silver electroded alumina (Ag/Al 2 O 3 ) substrates by spin coating technique or screen printing technique. The thickness of the film was in the range of 2–10 μm. The key point of the process is to disperse fine-grained BST ceramic powders prepared by high energy ball mill into BST sol solution to form a slurry for spin coating and screen printing. In order to enhance the stability of the slurry and to avoid crack formation of the thick film, organic macromolecular poly-vinylpyrrolidone (PVP) was added to the sol solution. The structure and surface morphology of the films were studied by X-ray diffraction and Scanning Electron Microscope (SEM) techniques. It is revealed that the thick films exhibit pure perovskite phase and are crack-free, dense and homogeneous. 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Glasses</subject><subject>Ceramic industries</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical industry and chemicals</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystallography and Scattering Methods</subject><subject>Electrochemistry</subject><subject>Electrotechnical and electronic ceramics</subject><subject>Exact sciences and technology</subject><subject>Glass</subject><subject>Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids)</subject><subject>Materials Science</subject><subject>Methods of deposition of films and coatings; film growth and epitaxy</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Palladium</subject><subject>Physics</subject><subject>Scanning electron microscopy</subject><subject>Screen printing</subject><subject>Silver</subject><subject>Sol gel process</subject><subject>Spin coating</subject><subject>Technical ceramics</subject><subject>Thick films</subject><issn>1385-3449</issn><issn>1573-8663</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kc1KHjEUhoeiUP8uoLtQUFfT5neSLItUWxDc1HXIJCcanZl8TfIt3PUeeodeSTN8UqFQV-fl5Dkv5-Ttug8EfyIYy8-FYMVo32SvKdW9ftcdECFZr4aB7TXNlOgZ5_p9d1jKA8ZYK04OusdLO-bobI1pQXbxCCZwde1MaJPTBnKNUFAKaLQ5bmdUak5LXVWN1S62Aqr30T2iEKe5oPEJzcnHEMGjkqbnX7_vYEIz1Pvkj7v9YKcCJy_1qLu9_Prj4lt_fXP1_eLLde84VrVnkquAuffYeQWS04F5OVIllfDO6kFSHXTgIQTNvSKECHBcS6VHQrGAgR115zvfdsDPLZRq5lgcTJNdIG2L0YQPAgvMGnn2JsmEUpyJ1fLjP-BD2ualXWGUIgPTjK8Q2UEup1IyBLPJcbb5yRBs1pTMLiWzyjUlo9vM6YuxLe3PQ7aLi-XvICV4IJrJxtEdV9rTcgf5dYH_m_8BE9ajIg</recordid><startdate>20081201</startdate><enddate>20081201</enddate><creator>Zhang, Hongfang</creator><creator>Zhang, Liangying</creator><creator>Yao, Xi</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7QF</scope></search><sort><creationdate>20081201</creationdate><title>Fabrication and electrical properties of barium strontium titanate thick films by modified sol–gel method</title><author>Zhang, Hongfang ; Zhang, Liangying ; Yao, Xi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-3748f04dd0cd8e74263d7b28785dca96729f9f4fff94d81115ec49789b1205e63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Aluminum oxide</topic><topic>Applied sciences</topic><topic>Barium strontium titanates</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Ceramic industries</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical industry and chemicals</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Crystallography and Scattering Methods</topic><topic>Electrochemistry</topic><topic>Electrotechnical and electronic ceramics</topic><topic>Exact sciences and technology</topic><topic>Glass</topic><topic>Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids)</topic><topic>Materials Science</topic><topic>Methods of deposition of films and coatings; film growth and epitaxy</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Palladium</topic><topic>Physics</topic><topic>Scanning electron microscopy</topic><topic>Screen printing</topic><topic>Silver</topic><topic>Sol gel process</topic><topic>Spin coating</topic><topic>Technical ceramics</topic><topic>Thick films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Hongfang</creatorcontrib><creatorcontrib>Zhang, Liangying</creatorcontrib><creatorcontrib>Yao, Xi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Aluminium Industry Abstracts</collection><jtitle>Journal of electroceramics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Hongfang</au><au>Zhang, Liangying</au><au>Yao, Xi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication and electrical properties of barium strontium titanate thick films by modified sol–gel method</atitle><jtitle>Journal of electroceramics</jtitle><stitle>J Electroceram</stitle><date>2008-12-01</date><risdate>2008</risdate><volume>21</volume><issue>1-4</issue><spage>503</spage><epage>507</epage><pages>503-507</pages><issn>1385-3449</issn><eissn>1573-8663</eissn><coden>JOELFJ</coden><abstract>A modified sol–gel method has been developed to prepare for the barium strontium titanate (Ba 0.6 Sr 0.4 TiO 3 , BST) thick films. 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subjects Aluminum oxide
Applied sciences
Barium strontium titanates
Building materials. Ceramics. Glasses
Ceramic industries
Ceramics
Characterization and Evaluation of Materials
Chemical industry and chemicals
Chemistry and Materials Science
Composites
Cross-disciplinary physics: materials science
rheology
Crystallography and Scattering Methods
Electrochemistry
Electrotechnical and electronic ceramics
Exact sciences and technology
Glass
Liquid phase epitaxy
deposition from liquid phases (melts, solutions, and surface layers on liquids)
Materials Science
Methods of deposition of films and coatings
film growth and epitaxy
Natural Materials
Optical and Electronic Materials
Palladium
Physics
Scanning electron microscopy
Screen printing
Silver
Sol gel process
Spin coating
Technical ceramics
Thick films
title Fabrication and electrical properties of barium strontium titanate thick films by modified sol–gel method
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