Three dimensional polymer bis(nitrilotriacetato)-samarium(III) hydrate: Hydrothermal synthesis and crystal structure
Hydrothermal reaction of Sm₂O₃ with nitrilotriacetic acid gives rise to a lanthanide coordination polymer, [Sm(NTA)(H₂O)] n (I). Its solid state structure has been characterized by elemental analysis and IR spectroscopy. X-ray single-crystal diffraction analysis indicates that I is a three-dimension...
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Veröffentlicht in: | Russian journal of inorganic chemistry 2010, Vol.55 (8), p.1234-1237 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Hydrothermal reaction of Sm₂O₃ with nitrilotriacetic acid gives rise to a lanthanide coordination polymer, [Sm(NTA)(H₂O)] n (I). Its solid state structure has been characterized by elemental analysis and IR spectroscopy. X-ray single-crystal diffraction analysis indicates that I is a three-dimensional coordination polymer with eight-coordinated Sm(III) ion. |
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ISSN: | 0036-0236 1531-8613 |
DOI: | 10.1134/S0036023610080139 |