N-heterocyclic carbene catalysed aerobic oxidation of aromatic aldehydes to aryl esters using boronic acids

The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.

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Veröffentlicht in:Organic & biomolecular chemistry 2012-01, Vol.10 (4), p.848-851
Hauptverfasser: Arde, Panjab, Ramanjaneyulu, B T, Reddy, Virsinha, Saxena, Apurv, Anand, R Vijaya
Format: Artikel
Sprache:eng
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Zusammenfassung:The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.
ISSN:1477-0520
1477-0539
DOI:10.1039/c1ob06566a