N-heterocyclic carbene catalysed aerobic oxidation of aromatic aldehydes to aryl esters using boronic acids
The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.
Gespeichert in:
Veröffentlicht in: | Organic & biomolecular chemistry 2012-01, Vol.10 (4), p.848-851 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions. |
---|---|
ISSN: | 1477-0520 1477-0539 |
DOI: | 10.1039/c1ob06566a |