Three self-penetrated, interlocked, and polycatenated supramolecular isomers via one-pot synthesis and crystallization

Three self-penetrated, interlocked, and polycatenated supramolecular isomers via one-pot synthesis and crystallization

Three supramolecular isomers, {[Cd(2)(TPOM)(hfipbb)(2)]·x/y/zsolvent}(n) (1-3), have been synthesized and characterized by one-pot reaction. Even though the compositions of 1-3 are the same, they generate different structures. Reactions over various time periods were found to influence the formation...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (5), p.681-683
Hauptverfasser: Hu, Jin-Song, Qin, Ling, Zhang, Ming-Dao, Yao, Xiao-Qiang, Li, Yi-Zhi, Guo, Zi-Jian, Zheng, He-Gen, Xue, Zi-Ling
Format: Artikel
Sprache:eng
Schlagworte:
Crystallization
Isomers
Synthesis
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Zusammenfassung:Three supramolecular isomers, {[Cd(2)(TPOM)(hfipbb)(2)]·x/y/zsolvent}(n) (1-3), have been synthesized and characterized by one-pot reaction. Even though the compositions of 1-3 are the same, they generate different structures. Reactions over various time periods were found to influence the formation of supramolecular isomers, and there is little influence on this system under other conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc16147d