Synthesis and structure of copoly(amide esters) based on cyclic carbonates and monofunctional isocyanates

The anionic copolymerization of a series of cyclic carbonates with phenylisocyanate is investigated in the presence of sodium caprolactam. The structure of the obtained copolymers is established, and the mechanism of interaction is suggested. The effect of a substituent in cyclocarbonates on the yie...

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Veröffentlicht in:	Protection of metals and physical chemistry of surfaces 2011-07, Vol.47 (4), p.478-483
Hauptverfasser:	Beilin, I. L., Arkhireev, V. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Caprolactam Carbonates Characterization and Evaluation of Materials Chemistry and Materials Science Copolymerization Copolymers Corrosion and Coatings Esters Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Metallic Materials Molecular and Supramolecular Structures at the Interfaces Physical chemistry Sodium Synthesis Tribology
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Zusammenfassung:	The anionic copolymerization of a series of cyclic carbonates with phenylisocyanate is investigated in the presence of sodium caprolactam. The structure of the obtained copolymers is established, and the mechanism of interaction is suggested. The effect of a substituent in cyclocarbonates on the yield of the resulting copolymeric product is shown.
ISSN:	2070-2051 2070-206X
DOI:	10.1134/S2070205111040046