Cu-Mn bimetallic catalyst for Huisgen [3+2]-cycloaddition

Cu-Mn bimetallic catalyst for Huisgen [3+2]-cycloaddition

Cu-Mn spinel oxide catalyst has been investigated for the ligand-free Huisgen [3+2] cycloaddition. The copper(i) species required in the cycloaddition reaction has been stabilized in the tetrahedral site of the spinel without the need of a stabilizing agent. The new catalyst is robust and can be reu...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2010-01, Vol.12 (9), p.1568-1572
Hauptverfasser: SYED KHALID YOUSUF, MUKHERJEE, Debaraj, SINGH, Baldev, MAITY, Sudip, SUBHASH CHANDRA TANEJA
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Cu-Mn spinel oxide catalyst has been investigated for the ligand-free Huisgen [3+2] cycloaddition. The copper(i) species required in the cycloaddition reaction has been stabilized in the tetrahedral site of the spinel without the need of a stabilizing agent. The new catalyst is robust and can be reused several times under MW conditions with negligible loss in catalytic activity.
ISSN:1463-9262
1463-9270
DOI:10.1039/c005088a