Highly chemoselective metal-free oxidation of sulfides with diluted H2O2 in a continuous flow reactor

Highly chemoselective metal-free oxidation of sulfides with diluted H2O2 in a continuous flow reactor

The oxidation of different aromatic sulfides catalyzed by Amberlite IR 120 H was performed with a very high efficiency in a continuous flow reactor. For the first time this reaction takes place under mild conditions using only 3% aqueous hydrogen peroxide and no metal catalyst.

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2011-01, Vol.13 (5), p.1121-1123
Hauptverfasser: MAGGI, Raimondo, CHITSAZ, Soheila, LOEBBECKE, Stefan, PISCOPO, Calogero G, SARTORI, Giovanni, SCHWARZER, Maud
Format: Artikel
Sprache:eng
Schlagworte:
Amberlite (trademark)
Applied sciences
Catalysis
Catalysts
Catalytic reactions
Chemical engineering
Chemistry
Continuous flow
Exact sciences and technology
General and physical chemistry
Hydrogen peroxide
Infrared radiation
Ion exchange
Oxidation
Reactors
Sulfides
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Zusammenfassung:The oxidation of different aromatic sulfides catalyzed by Amberlite IR 120 H was performed with a very high efficiency in a continuous flow reactor. For the first time this reaction takes place under mild conditions using only 3% aqueous hydrogen peroxide and no metal catalyst.
ISSN:1463-9262
1463-9270
DOI:10.1039/c0gc00887g