BOP-mediated one-pot synthesis of C5-symmetric macrocyclic pyridone pentamers

We report here, for the first time, the BOP-mediated one-pot macrocyclization that is facilitated and guided by internally placed intramolecular H-bonds to allow for the highly selective formation of five-residue cation-binding macrocycles.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2011-12, Vol.47 (46), p.12488-12490
Hauptverfasser:	Du, Zhiyun, Ren, Changliang, Ye, Ruijuan, Shen, Jie, Maurizot, Victor, Lu, Yujin, Wang, Jian, Zeng, Huaqiang
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Chemistry Techniques, Synthetic - methods Macrocyclic compounds Macrocyclic Compounds - chemical synthesis Macrocyclic Compounds - chemistry Models, Molecular Molecular Conformation Organophosphorus Compounds - chemistry Polymers - chemical synthesis Polymers - chemistry Pyridones - chemistry Synthesis
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Beschreibung
Zusammenfassung:	We report here, for the first time, the BOP-mediated one-pot macrocyclization that is facilitated and guided by internally placed intramolecular H-bonds to allow for the highly selective formation of five-residue cation-binding macrocycles.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c1cc14377h