Ruthenium-Catalyzed Conversion of Levulinic Acid to Pyrrolidines by Reductive Amination

Combo deal: An aqueous solution of levulinic acid (LA) and formic acid (FA) derived from biomass‐based carbohydrates can be converted efficiently to pyrrolidines via a ruthenium catalyst without need for an energy‐intensive separation of LA or an external H2 source. The ruthenium catalyst combines t...

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Veröffentlicht in:	ChemSusChem 2011-11, Vol.4 (11), p.1578-1581
Hauptverfasser:	Huang, Yao-Bing, Dai, Jian-Jun, Deng, Xiao-Jian, Qu, Yan-Chao, Guo, Qing-Xiang, Fu, Yao
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination amines Catalysis homogeneous catalysis Levulinic Acids - chemistry Oxidation-Reduction Pyrrolidines - chemistry renewable resources ruthenium Ruthenium - chemistry
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creator	Huang, Yao-Bing Dai, Jian-Jun Deng, Xiao-Jian Qu, Yan-Chao Guo, Qing-Xiang Fu, Yao
description	Combo deal: An aqueous solution of levulinic acid (LA) and formic acid (FA) derived from biomass‐based carbohydrates can be converted efficiently to pyrrolidines via a ruthenium catalyst without need for an energy‐intensive separation of LA or an external H2 source. The ruthenium catalyst combines two processes: decomposition of FA to H2 and reductive amination of LA with an amine.
doi_str_mv	10.1002/cssc.201100344
format	Article
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subjects	Amination amines Catalysis homogeneous catalysis Levulinic Acids - chemistry Oxidation-Reduction Pyrrolidines - chemistry renewable resources ruthenium Ruthenium - chemistry
title	Ruthenium-Catalyzed Conversion of Levulinic Acid to Pyrrolidines by Reductive Amination
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