Indium as an ideal functional dopant for a proton-conducting solid oxide fuel cell
A high In-dopant level BaCeO 3 material was used as an electrolyte for a proton-conducting solid oxide fuel cell (SOFC). Indium behaved as an ideal dopant for BaCeO 3, which improved both the chemical stability and sinterability for BaCeO 3 greatly. The anode supported BaCe 0.7In 0.3O 3− δ (BCI30) m...
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Veröffentlicht in: | International journal of hydrogen energy 2009-03, Vol.34 (5), p.2421-2425 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A high In-dopant level BaCeO
3 material was used as an electrolyte for a proton-conducting solid oxide fuel cell (SOFC). Indium behaved as an ideal dopant for BaCeO
3, which improved both the chemical stability and sinterability for BaCeO
3 greatly. The anode supported BaCe
0.7In
0.3O
3−
δ
(BCI30) membrane reached dense after sintering at 1100
°C, much lower than the sintering temperature for other BaCeO
3-based materials. Additionally, the BCI30 membrane showed adequate chemical stability against CO
2 compared with the traditional rare earth doped BaCeO
3. The BCI30-based fuel cell also showed a reasonable cell performance and a good long-term stability under the operating condition. Besides, the LaSr
3Co
1.5Fe
1.5O
10−
δ
(LSCF) was also evaluated as a potential cathode candidate for a proton-conducting SOFC. |
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ISSN: | 0360-3199 1879-3487 |
DOI: | 10.1016/j.ijhydene.2008.12.087 |