Optical and electrical properties of Nd-doped BiFeO3 thin films and heterostructures

High quality BiFeO3 (BFO) and Bi0.9Nd0.1FeO3 (BNFO) thin films (d = 150‐350 nm) were grown at 650‐750°C by RF sputtering on dielectric (SrTiO3; ZrO2) and conducting (Nb‐doped SrTiO3(100); n‐type Si) substrates. A direct band gap at 2.57 eV and 2.62 eV (at T =295 K) have been estimated for the BFO/YS...

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Veröffentlicht in:Physica status solidi. C 2009-12, Vol.6 (12), p.2746-2749
Hauptverfasser: Vengalis, Bonifacas, Devenson, Jelena, Oginskis, Antanas K., Lisauskas, Vaclovas, Anisimovas, Fiodoras, Butkute, Renata, Dapkus, Leonas
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container_issue 12
container_start_page 2746
container_title Physica status solidi. C
container_volume 6
creator Vengalis, Bonifacas
Devenson, Jelena
Oginskis, Antanas K.
Lisauskas, Vaclovas
Anisimovas, Fiodoras
Butkute, Renata
Dapkus, Leonas
description High quality BiFeO3 (BFO) and Bi0.9Nd0.1FeO3 (BNFO) thin films (d = 150‐350 nm) were grown at 650‐750°C by RF sputtering on dielectric (SrTiO3; ZrO2) and conducting (Nb‐doped SrTiO3(100); n‐type Si) substrates. A direct band gap at 2.57 eV and 2.62 eV (at T =295 K) have been estimated for the BFO/YSZ and BNFO/YSZ films from optical transmittance spectra while an unset of weak absorption has been indicated for the films at 2.20 eV. Transverse electrical transport of the (BFO, BNFO)/(STON, Si) heterostructures revealed nonlinear current versus voltage behavior and clearly defined rectifying properties. Schottky junction model has been applied for the heterojunctions at T =300 K although complicated shape of I‐U curves demonstrated increasing role of space charge limited current with T decreasing down to 78 K. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssc.200982540
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source Wiley Online Library Journals Frontfile Complete
subjects 61.05.cp
68.55.−a
73.40.Lq
77.84.Bw
78.66.Li
81.15.Cd
Electric potential
Electrical junctions
Heterostructures
Reproduction
Silicon substrates
Thin films
Yttria stabilized zirconia
Zirconium dioxide
title Optical and electrical properties of Nd-doped BiFeO3 thin films and heterostructures
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