Microstructure and hydrogen storage characteristics of nanocrystalline Mg + x wt% LaMg sub(2Ni (x = 0-30) composites)
The nanocrystalline Mg + x wt% LaMg sub(2Ni (x = 0, 5, 10, 20, 30) composites were prepared by reactive ball-milling, their microstructure and hydrogen storage characteristics were investigated. The results show that the addition of LaMg) sub(2)Ni improves the hydriding rate and capacity. The hydrid...
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Veröffentlicht in: | International journal of hydrogen energy 2010-04, Vol.35 (7), p.2786-2790 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The nanocrystalline Mg + x wt% LaMg sub(2Ni (x = 0, 5, 10, 20, 30) composites were prepared by reactive ball-milling, their microstructure and hydrogen storage characteristics were investigated. The results show that the addition of LaMg) sub(2)Ni improves the hydriding rate and capacity. The hydriding capacity of the Mg + x wt% LaMg sub(2Ni (x = 5, 10, 20, 30) composites are all above 4.1 wt% at 120 degree C and above 4.3 wt% at 180 degree C within 6000 s. Moreover, the addition of LaMg) sub(2)Ni also improves the dehydriding performance of the composites. The main reason for the improvement of hydriding/dehydriding properties investigated by XRD and SEM shows that the synergistic effect among the multiphase nanocrystalline Mg-based structures make hydrogen easily absorbed/desorbed on the interface of the matrix. |
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ISSN: | 0360-3199 |
DOI: | 10.1016/j.ijhydene.2009.05.024 |