Polylactide/exfoliated graphite nanocomposites with enhanced thermal stability, mechanical modulus, and electrical conductivity
We have prepared a series of polylactide/exfoliated graphite (PLA/EG) nanocomposites by melt-compounding and investigated their morphology, structures, thermal stability, mechanical, and electrical properties. For PLA/EG nanocomposites, EG was prepared by the acid treatment and following rapid therm...
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Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2010-04, Vol.48 (8), p.850-858 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We have prepared a series of polylactide/exfoliated graphite (PLA/EG) nanocomposites by melt-compounding and investigated their morphology, structures, thermal stability, mechanical, and electrical properties. For PLA/EG nanocomposites, EG was prepared by the acid treatment and following rapid thermal expansion of micron-sized crystalline natural graphite (NG), and it was characterized to be composed of disordered graphite nanoplatelets. It was revealed that graphite nanoplatelets of PLA/EG nanocomposites were dispersed homogeneously in the PLA matrix without forming the crystalline aggregates, unlike PLA/NG composites. Thermal degradation temperatures of PLA/EG nanocomposites increased substantially with the increment of EG content up to ~3 wt %, whereas those of PLA/NG composites remained constant regardless of the NG content. For instance, thermal degradation temperature of PLA/EG nanocomposite with only 0.5 wt % EG was improved by ~10 K over PLA homopolymer. Young's moduli of PLA/EG nanocomposites increased noticeably with the increment of EG content up to ~3 wt %, compared with PLA/NG composites. The percolation threshold for electrical conduction of PLA/EG nanocomposites was found to be at 3-5 wt % EG, which is far lower graphite content than that (10-15 wt % NG) of PLA/NG composites. |
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ISSN: | 0887-6266 1099-0488 1099-0488 |
DOI: | 10.1002/polb.21956 |