Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol
As a viable alternative to the petrochemical polyols in polyurethanes (PUs), a new soybean oil‐based polyol (PSBO) with high functionality of hydroxyl groups and built‐in (preformed) urethane bonds was introduced. At first, a facile and improved method was developed for the transformation of epoxidi...
Gespeichert in:
| Veröffentlicht in: | Polymers for advanced technologies 2010-02, Vol.21 (2), p.118-127 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 127 |
|---|---|
| container_issue | 2 |
| container_start_page | 118 |
| container_title | Polymers for advanced technologies |
| container_volume | 21 |
| creator | Jalilian, Mehrdad Yeganeh, Hamid Haghighi, Mehdi Nekoomanesh |
| description | As a viable alternative to the petrochemical polyols in polyurethanes (PUs), a new soybean oil‐based polyol (PSBO) with high functionality of hydroxyl groups and built‐in (preformed) urethane bonds was introduced. At first, a facile and improved method was developed for the transformation of epoxidized soybean oil (ESBO) to carbonated soybean oil (CSBO). Then ring‐opening reaction of carbonated oil with ethanolamine (ETA) led to the polyol. After characterization by conventional spectroscopic and analytical methods, PSBO was used for the formulation of novel one‐pack PU electroinsulating wire enamels. Tunable mechanical, thermal, and electrical properties for the final PUs were achieved by replacing 10 wt% of PSBO with poly(propylene glycol) (PPG) at different number average molecular weights of 725, 1000, 2000, 4000. Investigation of the results showed that these soy‐based PUs offer excellent thermal and electrical insulating properties. Copyright © 2009 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/pat.1406 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_901658035</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>901658035</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3676-e13a1521cf4511c0dda1936441bc3ac2bf207368b102d218ef1d2cb2829a9f793</originalsourceid><addsrcrecordid>eNqFkUtLAzEUhQdRsD7An5CdbkZzk3kutVgVfBStuAyZzB2NppMxmarVP29qRXAhru7jfPfA5UTRDtB9oJQddLLfh4RmK9EAaFnGkBawuugTFueQ5OvRhvePlAatzAfRx9hhJ53stW2JbGuiHsKkenT6fbm0Demsmc8c9g-yRYIGVe-0kobo1s9MoNp7ouxX9aQOly9Yk8bZKWntCxri7bxCGZy0iSvpg7gwtGYrWmuk8bj9XTej29HxZHgan1-dnA0Pz2PFszyLEbiElIFqkhRA0bqWUPIsSaBSXCpWNYzmPCsqoKxmUGADNVMVK1gpyyYv-Wa0u_TtnH2eoe_FVHuFxoR37MyLkkKWFpSn_5JFQbOUJ5wGcm9JKme9d9iIzumpdHMBVCyCECEIsQgioPESfdUG539yYnw4-c1r3-PbDy_dk8hynqfi7vJEHI1G1zejCypu-Cdc1ZtU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>880653430</pqid></control><display><type>article</type><title>Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol</title><source>Access via Wiley Online Library</source><creator>Jalilian, Mehrdad ; Yeganeh, Hamid ; Haghighi, Mehdi Nekoomanesh</creator><creatorcontrib>Jalilian, Mehrdad ; Yeganeh, Hamid ; Haghighi, Mehdi Nekoomanesh</creatorcontrib><description>As a viable alternative to the petrochemical polyols in polyurethanes (PUs), a new soybean oil‐based polyol (PSBO) with high functionality of hydroxyl groups and built‐in (preformed) urethane bonds was introduced. At first, a facile and improved method was developed for the transformation of epoxidized soybean oil (ESBO) to carbonated soybean oil (CSBO). Then ring‐opening reaction of carbonated oil with ethanolamine (ETA) led to the polyol. After characterization by conventional spectroscopic and analytical methods, PSBO was used for the formulation of novel one‐pack PU electroinsulating wire enamels. Tunable mechanical, thermal, and electrical properties for the final PUs were achieved by replacing 10 wt% of PSBO with poly(propylene glycol) (PPG) at different number average molecular weights of 725, 1000, 2000, 4000. Investigation of the results showed that these soy‐based PUs offer excellent thermal and electrical insulating properties. Copyright © 2009 John Wiley & Sons, Ltd.</description><identifier>ISSN: 1042-7147</identifier><identifier>ISSN: 1099-1581</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.1406</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Carbonation ; coatings ; crosslinking ; electrical insulation ; Electrical properties ; Mathematical analysis ; Polyols ; Polyurethane resins ; polyurethanes ; renewable resources ; Soybeans ; Transformations ; Urethanes</subject><ispartof>Polymers for advanced technologies, 2010-02, Vol.21 (2), p.118-127</ispartof><rights>Copyright © 2009 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3676-e13a1521cf4511c0dda1936441bc3ac2bf207368b102d218ef1d2cb2829a9f793</citedby><cites>FETCH-LOGICAL-c3676-e13a1521cf4511c0dda1936441bc3ac2bf207368b102d218ef1d2cb2829a9f793</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpat.1406$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpat.1406$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Jalilian, Mehrdad</creatorcontrib><creatorcontrib>Yeganeh, Hamid</creatorcontrib><creatorcontrib>Haghighi, Mehdi Nekoomanesh</creatorcontrib><title>Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol</title><title>Polymers for advanced technologies</title><addtitle>Polym. Adv. Technol</addtitle><description>As a viable alternative to the petrochemical polyols in polyurethanes (PUs), a new soybean oil‐based polyol (PSBO) with high functionality of hydroxyl groups and built‐in (preformed) urethane bonds was introduced. At first, a facile and improved method was developed for the transformation of epoxidized soybean oil (ESBO) to carbonated soybean oil (CSBO). Then ring‐opening reaction of carbonated oil with ethanolamine (ETA) led to the polyol. After characterization by conventional spectroscopic and analytical methods, PSBO was used for the formulation of novel one‐pack PU electroinsulating wire enamels. Tunable mechanical, thermal, and electrical properties for the final PUs were achieved by replacing 10 wt% of PSBO with poly(propylene glycol) (PPG) at different number average molecular weights of 725, 1000, 2000, 4000. Investigation of the results showed that these soy‐based PUs offer excellent thermal and electrical insulating properties. Copyright © 2009 John Wiley & Sons, Ltd.</description><subject>Carbonation</subject><subject>coatings</subject><subject>crosslinking</subject><subject>electrical insulation</subject><subject>Electrical properties</subject><subject>Mathematical analysis</subject><subject>Polyols</subject><subject>Polyurethane resins</subject><subject>polyurethanes</subject><subject>renewable resources</subject><subject>Soybeans</subject><subject>Transformations</subject><subject>Urethanes</subject><issn>1042-7147</issn><issn>1099-1581</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkUtLAzEUhQdRsD7An5CdbkZzk3kutVgVfBStuAyZzB2NppMxmarVP29qRXAhru7jfPfA5UTRDtB9oJQddLLfh4RmK9EAaFnGkBawuugTFueQ5OvRhvePlAatzAfRx9hhJ53stW2JbGuiHsKkenT6fbm0Demsmc8c9g-yRYIGVe-0kobo1s9MoNp7ouxX9aQOly9Yk8bZKWntCxri7bxCGZy0iSvpg7gwtGYrWmuk8bj9XTej29HxZHgan1-dnA0Pz2PFszyLEbiElIFqkhRA0bqWUPIsSaBSXCpWNYzmPCsqoKxmUGADNVMVK1gpyyYv-Wa0u_TtnH2eoe_FVHuFxoR37MyLkkKWFpSn_5JFQbOUJ5wGcm9JKme9d9iIzumpdHMBVCyCECEIsQgioPESfdUG539yYnw4-c1r3-PbDy_dk8hynqfi7vJEHI1G1zejCypu-Cdc1ZtU</recordid><startdate>201002</startdate><enddate>201002</enddate><creator>Jalilian, Mehrdad</creator><creator>Yeganeh, Hamid</creator><creator>Haghighi, Mehdi Nekoomanesh</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201002</creationdate><title>Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol</title><author>Jalilian, Mehrdad ; Yeganeh, Hamid ; Haghighi, Mehdi Nekoomanesh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3676-e13a1521cf4511c0dda1936441bc3ac2bf207368b102d218ef1d2cb2829a9f793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Carbonation</topic><topic>coatings</topic><topic>crosslinking</topic><topic>electrical insulation</topic><topic>Electrical properties</topic><topic>Mathematical analysis</topic><topic>Polyols</topic><topic>Polyurethane resins</topic><topic>polyurethanes</topic><topic>renewable resources</topic><topic>Soybeans</topic><topic>Transformations</topic><topic>Urethanes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jalilian, Mehrdad</creatorcontrib><creatorcontrib>Yeganeh, Hamid</creatorcontrib><creatorcontrib>Haghighi, Mehdi Nekoomanesh</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jalilian, Mehrdad</au><au>Yeganeh, Hamid</au><au>Haghighi, Mehdi Nekoomanesh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol</atitle><jtitle>Polymers for advanced technologies</jtitle><addtitle>Polym. Adv. Technol</addtitle><date>2010-02</date><risdate>2010</risdate><volume>21</volume><issue>2</issue><spage>118</spage><epage>127</epage><pages>118-127</pages><issn>1042-7147</issn><issn>1099-1581</issn><eissn>1099-1581</eissn><abstract>As a viable alternative to the petrochemical polyols in polyurethanes (PUs), a new soybean oil‐based polyol (PSBO) with high functionality of hydroxyl groups and built‐in (preformed) urethane bonds was introduced. At first, a facile and improved method was developed for the transformation of epoxidized soybean oil (ESBO) to carbonated soybean oil (CSBO). Then ring‐opening reaction of carbonated oil with ethanolamine (ETA) led to the polyol. After characterization by conventional spectroscopic and analytical methods, PSBO was used for the formulation of novel one‐pack PU electroinsulating wire enamels. Tunable mechanical, thermal, and electrical properties for the final PUs were achieved by replacing 10 wt% of PSBO with poly(propylene glycol) (PPG) at different number average molecular weights of 725, 1000, 2000, 4000. Investigation of the results showed that these soy‐based PUs offer excellent thermal and electrical insulating properties. Copyright © 2009 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pat.1406</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-7147 |
| ispartof | Polymers for advanced technologies, 2010-02, Vol.21 (2), p.118-127 |
| issn | 1042-7147 1099-1581 1099-1581 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_901658035 |
| source | Access via Wiley Online Library |
| subjects | Carbonation coatings crosslinking electrical insulation Electrical properties Mathematical analysis Polyols Polyurethane resins polyurethanes renewable resources Soybeans Transformations Urethanes |
| title | Preparation and characterization of polyurethane electrical insulating coatings derived from novel soybean oil-based polyol |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T23%3A40%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20and%20characterization%20of%20polyurethane%20electrical%20insulating%20coatings%20derived%20from%20novel%20soybean%20oil-based%20polyol&rft.jtitle=Polymers%20for%20advanced%20technologies&rft.au=Jalilian,%20Mehrdad&rft.date=2010-02&rft.volume=21&rft.issue=2&rft.spage=118&rft.epage=127&rft.pages=118-127&rft.issn=1042-7147&rft.eissn=1099-1581&rft_id=info:doi/10.1002/pat.1406&rft_dat=%3Cproquest_cross%3E901658035%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=880653430&rft_id=info:pmid/&rfr_iscdi=true |