Graft polymerization of acrylonitrile onto paper and characterization of the grafted product
The chemical graft copolymerization reaction of acrylonitrile (AN) onto paper sheet was performed. The effect of initiator concentration, monomer concentration, and temperature on the reaction rate was studied. The reaction rate equation of the graft copolymerization reaction is found to be RP = K2...
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| Veröffentlicht in: | Journal of applied polymer science 2011-05, Vol.120 (3), p.1411-1419 |
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| creator | Sayyah, S. M. Abd El-Salam, H. M. Khaliel, A. B. Mohamed, E. H. |
| description | The chemical graft copolymerization reaction of acrylonitrile (AN) onto paper sheet was performed. The effect of initiator concentration, monomer concentration, and temperature on the reaction rate was studied. The reaction rate equation of the graft copolymerization reaction is found to be RP = K2 [initiator]0.54[monomer]1.13. The apparent activation energy (Ea) of the copolymerization reaction is found to be 35.99 KJ/mol. The infrared characteristic absorption bands for cellulosic paper structure and the paper gr‐AN are studied. Tensile break load, porosity, and burst strength were measured for the grafted and pure paper sheet. It was found that the mechanical properties are improved by grafting. The chemical resistance of the graft product against strong acid (HCl), strong alkali (NaOH), polar and nonpolar solvents was investigated. It was found that the resistance to these chemicals is enhanced by grafting. From the TGA and DTA data, it is clear that the grafted paper sheet is more thermally stable than pure paper sheet. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 |
| doi_str_mv | 10.1002/app.33054 |
| format | Article |
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M. ; Abd El-Salam, H. M. ; Khaliel, A. B. ; Mohamed, E. H.</creator><creatorcontrib>Sayyah, S. M. ; Abd El-Salam, H. M. ; Khaliel, A. B. ; Mohamed, E. H.</creatorcontrib><description>The chemical graft copolymerization reaction of acrylonitrile (AN) onto paper sheet was performed. The effect of initiator concentration, monomer concentration, and temperature on the reaction rate was studied. The reaction rate equation of the graft copolymerization reaction is found to be RP = K2 [initiator]0.54[monomer]1.13. The apparent activation energy (Ea) of the copolymerization reaction is found to be 35.99 KJ/mol. The infrared characteristic absorption bands for cellulosic paper structure and the paper gr‐AN are studied. Tensile break load, porosity, and burst strength were measured for the grafted and pure paper sheet. It was found that the mechanical properties are improved by grafting. The chemical resistance of the graft product against strong acid (HCl), strong alkali (NaOH), polar and nonpolar solvents was investigated. It was found that the resistance to these chemicals is enhanced by grafting. From the TGA and DTA data, it is clear that the grafted paper sheet is more thermally stable than pure paper sheet. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><identifier>ISSN: 0021-8995</identifier><identifier>ISSN: 1097-4628</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.33054</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>acrylonitrile ; Acrylonitriles ; Applied sciences ; Bursting strength ; Cellulose and derivatives ; characterization ; Copolymerization ; Exact sciences and technology ; graft copolymerization ; Grafting ; Materials science ; Mathematical analysis ; Natural polymers ; paper sheet ; Physicochemistry of polymers ; Polymerization ; Polymers ; Reproduction</subject><ispartof>Journal of applied polymer science, 2011-05, Vol.120 (3), p.1411-1419</ispartof><rights>Copyright © 2010 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4344-e8c35c0875639b57fd33471ab55f4279e317ff2af9018babe6426c5701d573703</citedby><cites>FETCH-LOGICAL-c4344-e8c35c0875639b57fd33471ab55f4279e317ff2af9018babe6426c5701d573703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.33054$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.33054$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23916979$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sayyah, S. M.</creatorcontrib><creatorcontrib>Abd El-Salam, H. M.</creatorcontrib><creatorcontrib>Khaliel, A. B.</creatorcontrib><creatorcontrib>Mohamed, E. H.</creatorcontrib><title>Graft polymerization of acrylonitrile onto paper and characterization of the grafted product</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The chemical graft copolymerization reaction of acrylonitrile (AN) onto paper sheet was performed. The effect of initiator concentration, monomer concentration, and temperature on the reaction rate was studied. The reaction rate equation of the graft copolymerization reaction is found to be RP = K2 [initiator]0.54[monomer]1.13. The apparent activation energy (Ea) of the copolymerization reaction is found to be 35.99 KJ/mol. The infrared characteristic absorption bands for cellulosic paper structure and the paper gr‐AN are studied. Tensile break load, porosity, and burst strength were measured for the grafted and pure paper sheet. It was found that the mechanical properties are improved by grafting. The chemical resistance of the graft product against strong acid (HCl), strong alkali (NaOH), polar and nonpolar solvents was investigated. It was found that the resistance to these chemicals is enhanced by grafting. From the TGA and DTA data, it is clear that the grafted paper sheet is more thermally stable than pure paper sheet. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><subject>acrylonitrile</subject><subject>Acrylonitriles</subject><subject>Applied sciences</subject><subject>Bursting strength</subject><subject>Cellulose and derivatives</subject><subject>characterization</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>graft copolymerization</subject><subject>Grafting</subject><subject>Materials science</subject><subject>Mathematical analysis</subject><subject>Natural polymers</subject><subject>paper sheet</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Reproduction</subject><issn>0021-8995</issn><issn>1097-4628</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp1kNFq2zAUhsVooWm6i76BoIzRCzeSZVnWZSlrNghZCimDUhAnsrS4dSxPUuiyp5-yZIEWeqNzoe__zuFH6JySK0pIPoK-v2KM8OIDGlAiRVaUeXWEBumPZpWU_ASdhvBECKWclAP0OPZgI-5du1kZ3_yB2LgOO4tB-03ruib6pjXYddHhHnrjMXQ11kvwoOOrQFwa_HMrMzXuvavXOp6hYwttMB_3c4jub7_Mb75mk-_jbzfXk0wXrCgyU2nGNakEL5lccGFrxgpBYcG5LXIhDaPC2hysJLRawMKURV5qLgituWCCsCH6vPOmvb_WJkS1aoI2bQudceugUq7kvBJVIi_ekE9u7bt0nKKclskm0jNElztKexeCN1b1vlmB3yhK1LZmlWpW_2pO7Ke9EYKG1nrodBMOgZxJWkohEzfacS-pz837QnU9m_03Z7tEE6L5fUiAf1bbQ7n6MR2r-cN0fHd7N1Fz9he_kJrI</recordid><startdate>20110505</startdate><enddate>20110505</enddate><creator>Sayyah, S. M.</creator><creator>Abd El-Salam, H. M.</creator><creator>Khaliel, A. B.</creator><creator>Mohamed, E. H.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110505</creationdate><title>Graft polymerization of acrylonitrile onto paper and characterization of the grafted product</title><author>Sayyah, S. M. ; Abd El-Salam, H. M. ; Khaliel, A. B. ; Mohamed, E. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4344-e8c35c0875639b57fd33471ab55f4279e317ff2af9018babe6426c5701d573703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>acrylonitrile</topic><topic>Acrylonitriles</topic><topic>Applied sciences</topic><topic>Bursting strength</topic><topic>Cellulose and derivatives</topic><topic>characterization</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>graft copolymerization</topic><topic>Grafting</topic><topic>Materials science</topic><topic>Mathematical analysis</topic><topic>Natural polymers</topic><topic>paper sheet</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Reproduction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sayyah, S. M.</creatorcontrib><creatorcontrib>Abd El-Salam, H. M.</creatorcontrib><creatorcontrib>Khaliel, A. B.</creatorcontrib><creatorcontrib>Mohamed, E. H.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sayyah, S. M.</au><au>Abd El-Salam, H. M.</au><au>Khaliel, A. B.</au><au>Mohamed, E. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graft polymerization of acrylonitrile onto paper and characterization of the grafted product</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2011-05-05</date><risdate>2011</risdate><volume>120</volume><issue>3</issue><spage>1411</spage><epage>1419</epage><pages>1411-1419</pages><issn>0021-8995</issn><issn>1097-4628</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The chemical graft copolymerization reaction of acrylonitrile (AN) onto paper sheet was performed. The effect of initiator concentration, monomer concentration, and temperature on the reaction rate was studied. The reaction rate equation of the graft copolymerization reaction is found to be RP = K2 [initiator]0.54[monomer]1.13. The apparent activation energy (Ea) of the copolymerization reaction is found to be 35.99 KJ/mol. The infrared characteristic absorption bands for cellulosic paper structure and the paper gr‐AN are studied. Tensile break load, porosity, and burst strength were measured for the grafted and pure paper sheet. It was found that the mechanical properties are improved by grafting. The chemical resistance of the graft product against strong acid (HCl), strong alkali (NaOH), polar and nonpolar solvents was investigated. It was found that the resistance to these chemicals is enhanced by grafting. From the TGA and DTA data, it is clear that the grafted paper sheet is more thermally stable than pure paper sheet. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.33054</doi><tpages>9</tpages></addata></record> |
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| subjects | acrylonitrile Acrylonitriles Applied sciences Bursting strength Cellulose and derivatives characterization Copolymerization Exact sciences and technology graft copolymerization Grafting Materials science Mathematical analysis Natural polymers paper sheet Physicochemistry of polymers Polymerization Polymers Reproduction |
| title | Graft polymerization of acrylonitrile onto paper and characterization of the grafted product |
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