Unprecedented reactivity of an aluminium hydride complex with ArNH2BH3: nucleophilic substitution versus deprotonation
Reaction of DIPPnacnacAlH(2) with DIPPNH(2)BH(3) did not give the anticipated deprotonation but nucleophilic substitution at B was observed instead. The product DIPPnacnacAl(BH(4))(2) was isolated and structurally characterized. Nucleophilic displacement at B might play a role in mechanistic pathway...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2011-11, Vol.47 (43), p.11945-11947 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Reaction of DIPPnacnacAlH(2) with DIPPNH(2)BH(3) did not give the anticipated deprotonation but nucleophilic substitution at B was observed instead. The product DIPPnacnacAl(BH(4))(2) was isolated and structurally characterized. Nucleophilic displacement at B might play a role in mechanistic pathways related to metal amidoborane complexes. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c1cc14689k |