Ground-based measurements of total ozone content by the infrared method

To interpret the ground-based measurements of the spectra of direct solar infrared radiation with the help of a Brucker Fourier-spectrometer, a technique for determining the total ozone content (TOC) was developed and implemented. The TOC was determined using six spectral intervals of an ozone-absorption band of 9.6 μm and the shortwave panel of a carbon-dioxide-absorption band of 15 μm, where the impact of other atmospheric parameters on the measured solar radiation was reduced to a minimum. The potential errors of the infrared method for determining the TOC for the chosen spectral scheme with the influence of measurement errors and vertical profiles of temperature are less than 1% for different signal-to-noise ratios and zenith angles of the sun. We analyzed 269 high-resolution (0.005–0.008 cm −1 ) spectra of solar infrared radiation measured in Peterhof over 52 days from March to November, 2009. The resulting values of TOC were compared with the results of independent ground-based TOC measurements in Voeikovo (Main Geophysical Observatory) using a Dobson spectrophotometer and an M-124 ozonometer, as well as with the Ozone Monitoring Instrument (OMI) satellite data. The mean errors between the results of TOC measurements with the help of the three ground-based probes constitute no more than 0.4%. The rms errors between data obtained by the Brucker spectrometer and the given satellite and ground-based probes constitute 3–4%. A comparison between different series of measurements indicated that the upper estimate for the error of TOC measurements by the Brucker spectrometer was 2.5–3% (when the possible spatial and temporal errors in measurements are disregarded). An analysis of the diurnal variations in the TOC measurements for stable atmospheric conditions yields an upper estimate of ∼3 DU (around 1%) for the random component of error in TOC measurements by the Brucker spectrometer.