A Sphere-in-Sphere Complex by Orthogonal Self-Assembly

Russian dolls: Two covalently tethered, curved bispyridinyl ligands and PdII ions have been shown to self‐assemble into a sphere‐in‐sphere complex (6.3 nm in diameter; see X‐ray structure). The two ligands did not form heteroleptic mixed complexes, but instead assembled into two distinct homogeneous...

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Veröffentlicht in:	Angewandte Chemie International Edition 2011-10, Vol.50 (44), p.10318-10321
Hauptverfasser:	Sun, Qing-Fu, Murase, Takashi, Sato, Sota, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Capsid - chemistry coordination modes Crystallography, X-Ray Dimethyl Sulfoxide - chemistry entropic effects Ligands N ligands Organometallic Compounds - chemistry palladium Platinum - chemistry self-assembly
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Russian dolls: Two covalently tethered, curved bispyridinyl ligands and PdII ions have been shown to self‐assemble into a sphere‐in‐sphere complex (6.3 nm in diameter; see X‐ray structure). The two ligands did not form heteroleptic mixed complexes, but instead assembled into two distinct homogeneous [M12L24] cuboctahedra, reminiscent of a double‐shell viral capsid.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201104670