A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell
A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, a...
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Veröffentlicht in: | Journal of power sources 2008-12, Vol.185 (2), p.909-912 |
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container_title | Journal of power sources |
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creator | Qin, H.Y. Liu, Z.X. Yin, W.X. Zhu, J.K. Li, Z.P. |
description | A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65
mW
cm
−2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC. |
doi_str_mv | 10.1016/j.jpowsour.2008.08.047 |
format | Article |
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mW
cm
−2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2008.08.047</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Borohydrides ; Carbon ; Catalysts ; Cathode ; Cathodes ; Cell performance ; Cobalt ; Cobalt polypyrrole carbon ; Direct borohydride fuel cell ; Energy ; Energy. Thermal use of fuels ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells ; Non-precious metal ; Polypyrroles ; Scanning electron microscopy</subject><ispartof>Journal of power sources, 2008-12, Vol.185 (2), p.909-912</ispartof><rights>2008 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c374t-9ba34f2489bd6bc40f669609755a978209b6c50d578bf339d694f522ff121f503</citedby><cites>FETCH-LOGICAL-c374t-9ba34f2489bd6bc40f669609755a978209b6c50d578bf339d694f522ff121f503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2008.08.047$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21256820$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Qin, H.Y.</creatorcontrib><creatorcontrib>Liu, Z.X.</creatorcontrib><creatorcontrib>Yin, W.X.</creatorcontrib><creatorcontrib>Zhu, J.K.</creatorcontrib><creatorcontrib>Li, Z.P.</creatorcontrib><title>A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell</title><title>Journal of power sources</title><description>A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65
mW
cm
−2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.</description><subject>Applied sciences</subject><subject>Borohydrides</subject><subject>Carbon</subject><subject>Catalysts</subject><subject>Cathode</subject><subject>Cathodes</subject><subject>Cell performance</subject><subject>Cobalt</subject><subject>Cobalt polypyrrole carbon</subject><subject>Direct borohydride fuel cell</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Non-precious metal</subject><subject>Polypyrroles</subject><subject>Scanning electron microscopy</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFUE1LxDAQDaLguvoXpBfx1JqPJmluLuIXLHhxzyFNEzYlu6lJq9Rfb8uuXoWBGWbezHvzALhGsEAQsbu2aLvwlcIQCwxhVcxR8hOwQBUnOeaUnoIFJLzKOafkHFyk1EIIEeJwATarTIda-T7rgh-7McbgzdTadSG5fqpUr_z4bZq52obGZDbErN-arHHR6D6rQwzbsYluHg3GZ9p4fwnOrPLJXB3zEmyeHt8fXvL12_Prw2qda8LLPhe1IqXFZSXqhtW6hJYxwaCYJCvBKwxFzTSFDeVVbQkRDROlpRhbizCyFJIluD3c7WL4GEzq5c6lWYDamzAkWQmGESVUTEh2QOoYUorGyi66nYqjRFDONspW_tooZxvlHCWfFm-OFCpp5W1Ue-3S3zZGmLJJ6YS7P-DM9O-nM1Em7cxem4NPsgnuP6of6JCM8Q</recordid><startdate>20081201</startdate><enddate>20081201</enddate><creator>Qin, H.Y.</creator><creator>Liu, Z.X.</creator><creator>Yin, W.X.</creator><creator>Zhu, J.K.</creator><creator>Li, Z.P.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20081201</creationdate><title>A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell</title><author>Qin, H.Y. ; Liu, Z.X. ; Yin, W.X. ; Zhu, J.K. ; Li, Z.P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c374t-9ba34f2489bd6bc40f669609755a978209b6c50d578bf339d694f522ff121f503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Borohydrides</topic><topic>Carbon</topic><topic>Catalysts</topic><topic>Cathode</topic><topic>Cathodes</topic><topic>Cell performance</topic><topic>Cobalt</topic><topic>Cobalt polypyrrole carbon</topic><topic>Direct borohydride fuel cell</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>Non-precious metal</topic><topic>Polypyrroles</topic><topic>Scanning electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qin, H.Y.</creatorcontrib><creatorcontrib>Liu, Z.X.</creatorcontrib><creatorcontrib>Yin, W.X.</creatorcontrib><creatorcontrib>Zhu, J.K.</creatorcontrib><creatorcontrib>Li, Z.P.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qin, H.Y.</au><au>Liu, Z.X.</au><au>Yin, W.X.</au><au>Zhu, J.K.</au><au>Li, Z.P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell</atitle><jtitle>Journal of power sources</jtitle><date>2008-12-01</date><risdate>2008</risdate><volume>185</volume><issue>2</issue><spage>909</spage><epage>912</epage><pages>909-912</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65
mW
cm
−2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2008.08.047</doi><tpages>4</tpages></addata></record> |
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subjects | Applied sciences Borohydrides Carbon Catalysts Cathode Cathodes Cell performance Cobalt Cobalt polypyrrole carbon Direct borohydride fuel cell Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Non-precious metal Polypyrroles Scanning electron microscopy |
title | A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell |
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