A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell

A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, a...

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Veröffentlicht in:Journal of power sources 2008-12, Vol.185 (2), p.909-912
Hauptverfasser: Qin, H.Y., Liu, Z.X., Yin, W.X., Zhu, J.K., Li, Z.P.
Format: Artikel
Sprache:eng
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Zusammenfassung:A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65 mW cm −2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.
ISSN:0378-7753
1873-2755
DOI:10.1016/j.jpowsour.2008.08.047