Low-temperature synthesis and microstructure-property study of single-phase yttrium iron garnet (YIG) nanocrystals via a rapid chemical coprecipitation

▶ Cubic and tetragonal phases of Y 3Fe 5O 12 appear around 650 °C with no trace of YFeO 3. ▶ A single cubic-phase of Y 3Fe 5O 12 nanocrystals is obtained around 750 °C. ▶ Y 3Fe 5O 12 nanocrystals grow almost linearly as a function of the temperature. ▶ Saturation magnetization shows a nonlinear increase from 0.24 to 24.54 emu g −1. Single-phase yttrium iron garnet (Y 3Fe 5O 12, YIG) nanocrystals have been synthesized via a rapid chemical coprecipitation process with reverse strike operations, followed by calcining the precipitates at the temperature around 750 °C. The formation of YIG nanocrystals from the amorphous precipitates and their microstructural features and magnetic properties were investigated by FT-IR, XRD, TG-DSC, FESEM, TEM and VSM. It has been found that the as-obtained precipitates could be thermally activated to directly form the crystalline phases of garnet structure around 650 °C, including cubic YIG and minor tetragonal YIG but no trace of YFeO 3, which was often involved during the synthesis of YIG or doped-YIG when a chemical coprecipitation method was used. The calcinations could make the tetragonal YIG entirely transform into the cubic phase at 750 °C and allow the crystallites of the latter to grow from ∼22 nm to ∼50 nm in size almost linearly as a function of the temperature ranging from 650 °C to 900 °C. Moreover, the room temperature saturation magnetization of the samples after calcinations at various temperatures showed a nonlinear increase from 0.24 emu g −1 to 24.54 emu g −1, which should be associated with the alignments of atomic magnetic moments in the materials from completely-disordered to partially-ordered firstly and further to completely-ordered and, in the last stage, mainly with the growing YIG nanocrystals.