Crystallization of Pb((Zn,Mg)1/3Nb2/3)O3-PbTiO3 Thin Films Via Immobilization of Pb2+ Ions During Sol-Gel Process
In this work, a modified sol–gel process using a crown ether, 18‐crown‐6 (18C6) as complexing agent to synthesize 0.77(0.6Pb(Zn1/3,Nb2/3)O3–0.4Pb(Mg1/3,Nb2/3)O3))–0.23PbTiO3(PZMN–PT) thin films is reported. With the addition of 18C6, perovskite phase directly crystallized from the amorphous films at...
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Veröffentlicht in: | Journal of the American Ceramic Society 2010-12, Vol.93 (12), p.4036-4040 |
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Sprache: | eng |
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Zusammenfassung: | In this work, a modified sol–gel process using a crown ether, 18‐crown‐6 (18C6) as complexing agent to synthesize 0.77(0.6Pb(Zn1/3,Nb2/3)O3–0.4Pb(Mg1/3,Nb2/3)O3))–0.23PbTiO3(PZMN–PT) thin films is reported. With the addition of 18C6, perovskite phase directly crystallized from the amorphous films at a temperature as low as 460°C and the crystallinity was significantly enhanced. The promotion of 18C6 on perovskite formation can be attributed to the immobilization of Pb2+ ions, which facilitates the columbite‐like crystallization route. The pure‐perovskite films obtained by annealing at 460°C exhibit the optical and electrical properties comparable to literature data. Our studies therefore indicate a general approach by using crown ethers as complexing agent to synthesize the thermodynamically unstable ferroelectric materials, such as PMN‐ and PZN‐based systems. |
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ISSN: | 0002-7820 1551-2916 |
DOI: | 10.1111/j.1551-2916.2010.03988.x |