New Water-Soluble Organic Capsules Are Effective in Controlling Excited-State Processes of Guest Molecules

Synthesis, inclusion properties, and ability to control excited-state properties of two water-soluble hosts are presented. These hosts surround the guest molecule(s) by forming a capsular assembly. By constraining the guest and by providing very little free space, the host is able to alter the excit...

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Veröffentlicht in:Organic letters 2011-10, Vol.13 (19), p.5092-5095
Hauptverfasser: Kulasekharan, Revathy, Ramamurthy, V
Format: Artikel
Sprache:eng
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Zusammenfassung:Synthesis, inclusion properties, and ability to control excited-state properties of two water-soluble hosts are presented. These hosts surround the guest molecule(s) by forming a capsular assembly. By constraining the guest and by providing very little free space, the host is able to alter the excited-state behavior of guest molecules. The excited-state chemistry and physics of guest molecules are distinctly different from those in organic solvents.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol201968w