Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

The first zwitterionic alkaline earth metal silanides featuring two naked silyl anions were synthesized and a combined structural and computational study on these zwitterions revealed a correlation between the energy of the HOMO and the degree of negative charge of the naked silyl anions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-10, Vol.47 (39), p.11089-11091
Hauptverfasser: Carlson, Bryan, Aquino, Adelia J A, Hope-Weeks, Louisa J, Whittlesey, Bruce, McNerney, Brian, Hase, William L, Krempner, Clemens
Format: Artikel
Sprache:eng
Schlagworte:
Alkaline earth metals
Anions
Charge
Computation
Correlation analysis
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Zusammenfassung:The first zwitterionic alkaline earth metal silanides featuring two naked silyl anions were synthesized and a combined structural and computational study on these zwitterions revealed a correlation between the energy of the HOMO and the degree of negative charge of the naked silyl anions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc13933a