Neo-Confused Porphyrins, a New Class of Porphyrin Isomers

Neo-Confused Porphyrins, a New Class of Porphyrin Isomers

Confused yet still diatropic: A new type of porphyrin isomer is reported where a pyrrole nitrogen is connected to one of the meso‐bridges. This system retains porphyrin‐like characteristics and reacts with nickel(II) acetate to generate a stable organometallic complex.

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Veröffentlicht in:Angewandte Chemie International Edition 2011-10, Vol.50 (41), p.9718-9721
Hauptverfasser: Lash, Timothy D., Lammer, Aaron D., Ferrence, Gregory M.
Format: Artikel
Sprache:eng
Schlagworte:
aromaticity
carbaporphyrinoids
indoles
porphyrinoids
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Beschreibung
Zusammenfassung:Confused yet still diatropic: A new type of porphyrin isomer is reported where a pyrrole nitrogen is connected to one of the meso‐bridges. This system retains porphyrin‐like characteristics and reacts with nickel(II) acetate to generate a stable organometallic complex.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201104826