A room temperature solution-phase method to synthesize β-Ni(OH) 2 nanoneedles

A simple room temperature solution-phase method has been employed to synthesize β-Ni(OH) 2 nanoneedles in the presence of a suitable cationic surfactant cetyltrimethylammonium bromide for the first time. The chemical composition and morphology of the as-prepared β-Ni(OH) 2 nanoneedles were character...

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Veröffentlicht in:Materials letters 2011-06, Vol.65 (11), p.1591-1594
Hauptverfasser: Wang, Wenzhong, Lu, Baoli, Wang, Yan, Zhang, Ning, Zhang, Guling
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Sprache:eng
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Zusammenfassung:A simple room temperature solution-phase method has been employed to synthesize β-Ni(OH) 2 nanoneedles in the presence of a suitable cationic surfactant cetyltrimethylammonium bromide for the first time. The chemical composition and morphology of the as-prepared β-Ni(OH) 2 nanoneedles were characterized by X-ray powder diffraction and transmission electron microscopy. The effect of surfactant and NH 4OH on the morphology and size of β-Ni(OH) 2 nanoparticles was discussed in detail. The growth mechanism of the as-synthesized nanoneedles was discussed based on the experimental results. The results indicate that the binding between CTAB and β-Ni(OH) 2 crystal nuclei inhibits crystal growth randomly and favors needle-like single crystal growth with their preferred facets.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2011.02.085