C-Fused Norrole: A Fused Corrole Isomer Bearing a N,C-Linked Bipyrrole Unit

C-Fused Norrole: A Fused Corrole Isomer Bearing a N,C-Linked Bipyrrole Unit

Oxidative cyclization of a doubly N-confused bilane afforded a N-confused N,C-linked corrole (N-confused norrole), which was readily oxidized to form a C-fused N,C-linked corrole (C-fused norrole).

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Veröffentlicht in:Journal of organic chemistry 2011-09, Vol.76 (18), p.7618-7622
Hauptverfasser: Toganoh, Motoki, Kawabe, Yasunori, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chromatography, Thin Layer
Cyclization
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Isomerism
Magnetic Resonance Spectroscopy
Organic chemistry
Oxidation-Reduction
Preparations and properties
Pyrroles - chemistry
Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
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Beschreibung
Zusammenfassung:Oxidative cyclization of a doubly N-confused bilane afforded a N-confused N,C-linked corrole (N-confused norrole), which was readily oxidized to form a C-fused N,C-linked corrole (C-fused norrole).
ISSN:0022-3263
1520-6904
DOI:10.1021/jo2014017