Thiadiazoloquinoxaline–Acetylene Containing Polymers as Semiconductors in Ambipolar Field Effect Transistors

Two conjugated copolymers, PPTQT and PTTQT, were developed based on thiadiazoloquinoxalines connected via ethynylene π-spacer to thiophene units. PPTQT showed maximum hole and electron mobility of 0.028 and 0.042 cm2/V s, respectively, being the first example of an ambipolar semiconducting material...

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Veröffentlicht in:Journal of the American Chemical Society 2011-09, Vol.133 (35), p.13898-13901
Hauptverfasser: Dallos, Timea, Beckmann, Dirk, Brunklaus, Gunther, Baumgarten, Martin
Format: Artikel
Sprache:eng
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Zusammenfassung:Two conjugated copolymers, PPTQT and PTTQT, were developed based on thiadiazoloquinoxalines connected via ethynylene π-spacer to thiophene units. PPTQT showed maximum hole and electron mobility of 0.028 and 0.042 cm2/V s, respectively, being the first example of an ambipolar semiconducting material bearing triple bonds in the polymer backbone.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja2057709