A Class of Benzene Backbone-Based Olefin–Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones

A Class of Benzene Backbone-Based Olefin–Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones

A class of readily available and easily tunable benzene backbone-based olefin–sulfoxide ligands was developed for the rhodium-catalyzed asymmetric conjugate addition reaction of arylboronic acids to enones with up to 97% yield and 97% ee.

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Veröffentlicht in:Journal of organic chemistry 2011-09, Vol.76 (17), p.7256-7262
Hauptverfasser: Xue, Feng, Li, Xincheng, Wan, Boshun
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
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Beschreibung
Zusammenfassung:A class of readily available and easily tunable benzene backbone-based olefin–sulfoxide ligands was developed for the rhodium-catalyzed asymmetric conjugate addition reaction of arylboronic acids to enones with up to 97% yield and 97% ee.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo2011472