Asymmetric photocycloaddition of naphthamide with a diene using the provisional molecular chirality in a chiral crystal

Asymmetric photocycloaddition of naphthamide with a diene using the provisional molecular chirality in a chiral crystal

N -(2-Methoxy-1-naphthoyl)piperidine afforded chiral crystals by spontaneous crystallization, and the molecular chirality of the crystals was retained after dissolving them in a cooled solvent. An asymmetric photocycloaddition reaction with a diene was performed using the provisional chiral molecula...

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Veröffentlicht in:Photochemical & photobiological sciences 2011-09, Vol.10 (9), p.1387-1389
Hauptverfasser: Sakamoto, Masami, Yagishita, Fumitoshi, Saito, Ayako, Kobaru, Shuichiro, Unosawa, Atsushi, Mino, Takashi, Fujita, Tsutomu
Format: Artikel
Sprache:eng
Schlagworte:
Biochemistry
Biomaterials
Chemistry
Communication
Physical Chemistry
Plant Sciences
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Zusammenfassung:N -(2-Methoxy-1-naphthoyl)piperidine afforded chiral crystals by spontaneous crystallization, and the molecular chirality of the crystals was retained after dissolving them in a cooled solvent. An asymmetric photocycloaddition reaction with a diene was performed using the provisional chiral molecular conformation derived from these chiral crystals.
ISSN:1474-905X
1474-9092
DOI:10.1039/c1pp05053b