Facile fullerene modification: FeCl3-mediated quantitative conversion of C60 to polyarylated fullerenes containing pentaaryl(chloro)[60]fullerenes
A facile, one-step reaction using inexpensive reagents has been developed for functionalization of [60]fullerene, where the reaction of C(60) with FeCl(3) in chlorobenzene proceeded at 25 °C with 100% conversion, yielding a mixture of polyarylated products containing pentaaryl(chloro)[60]fullerene,...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2011-09, Vol.9 (18), p.6417-6421 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A facile, one-step reaction using inexpensive reagents has been developed for functionalization of [60]fullerene, where the reaction of C(60) with FeCl(3) in chlorobenzene proceeded at 25 °C with 100% conversion, yielding a mixture of polyarylated products containing pentaaryl(chloro)[60]fullerene, C(60)(C(6)H(4)Cl)(5)Cl (up to 29%) and other polyarylated fullerenes (number of aryl groups is in a range from 5 to 10). |
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| ISSN: | 1477-0539 |
| DOI: | 10.1039/c1ob05895a |