Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be cruci...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (33), p.9456-9458
Hauptverfasser: Jiménez-Aquino, Agustín, Flegeau, Emmanuel Ferrer, Schneider, Uwe, Kobayashi, Shū
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Catalysis
Catalysts
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Zusammenfassung:We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc13348a