Reversible Luminescence Switching of a Redox-Active Ferrocene–Europium Dyad

The copper-catalyzed cycloaddition reaction between a propargyl-appended europium complex and azidomethylferrocene yields a d–f dyad whose photophysical properties can be reversibly switched by varying the oxidation state of the ferrocene chromophore.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2011-08, Vol.133 (31), p.11847-11849
Hauptverfasser:	Tropiano, Manuel, Kilah, Nathan L, Morten, Michael, Rahman, Habibur, Davis, Jason J, Beer, Paul D, Faulkner, Stephen
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Copper - chemistry Cyclization Europium - chemistry Ferrous Compounds - chemistry Luminescence Metallocenes Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The copper-catalyzed cycloaddition reaction between a propargyl-appended europium complex and azidomethylferrocene yields a d–f dyad whose photophysical properties can be reversibly switched by varying the oxidation state of the ferrocene chromophore.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja203069s