Design, synthesis and characterization of a highly luminescent Eu-complex monomer featuring thenoyltrifluoroacetone and 5-acryloxyethoxymethyl-8-hydroxyquinoline

A multi-functional ligand, 5-acryloxyethoxymethyl-8-hydroxyquinoline (Hamq), was synthesized, which contained a polymerizable C=C double bond for the copolymerization with other vinyl monomers and acted as photon antenna able to transfer energy to Eu 3+ ions effectively. The triplet state energy of Hamq was determined to be 22,370 cm −1 via the phosphorescence spectra of Hamq and its gadolinium complex. The title complex monomer Eu(tta) 2(amq) was prepared by coordination reaction of Hamq with europium isopropoxide and 2-thenoyltrifluoroacetone (Htta) in dry organic solvents under argon atmosphere and characterized by elemental analysis and IR spectrum. The photophysical properties of the complex were studied in detail with UV–vis, luminescence spectra, luminescence lifetime and quantum yield. The complex exhibited nearly monochromatic red emission at 612 nm, a remarkable luminescence quantum yield at room temperature (30.6%) upon ligand excitation and a long 5D 0 lifetime (389 μs), which indicated that the ligand Hamq could sensitize the luminescence of Eu(III) ion efficiently in Eu(tta) 2(amq), resulting in a strong luminescence of its copolymer poly[MMA- co-Eu(TTA) 2(amq)] under UV excitation. The excellent luminescence properties of the complex made it not only a promising light-conversion molecular device but also an excellent luminescent monomer. ►iWe designed and synthesized a highly luminescent Eu-complex monomer. ► Quantum yield and lifetime of the complex are 30.6% and 389 μs, respectively. ► Excellent luminescence of the complex made it an excellent luminescent monomer.