New Frontiers in Materials Science Opened by Ionic Liquids

Ionic liquids (ILs) including ambient‐temperature molten salts, which exist in the liquid state even at room temperature, have a long research history. However, their applications were once limited because ILs were considered as highly moisture‐sensitive solvents that should be handled in a glove box. After the first synthesis of moisture‐stable ILs in 1992, their unique physicochemical properties became known in all scientific fields. ILs are composed solely of ions and exhibit several specific liquid‐like properties, e.g., some ILs enable dissolution of insoluble bio‐related materials and the use as tailor‐made lubricants in industrial applications under extreme physicochemical conditions. Hybridization of ILs and other materials provides quasi‐solid materials, which can be used to fabricate highly functional devices. ILs are also used as reaction media for electrochemical and chemical synthesis of nanomaterials. In addition, the negligible vapor pressure of ILs allows the fabrication of electrochemical devices that are operated under ambient conditions, and many liquid‐vacuum technologies, such as X‐ray photoelectron spectroscopy (XPS) analysis of liquids, electron microscopy of liquids, and sputtering and physical vapor deposition onto liquids. In this article, we review recent studies on ILs that are employed as functional advanced materials, advanced mediums for materials production, and components for preparing highly functional materials. Ionic liquids, which exhibit unusual physicochemical properties, such as negligible vapor pressure and high ionic conductivity, are a revolutionary liquid material as well as a state‐of‐the‐art solvent. In recent years, research in ionic liquid science and technology has produced many novel functional materials and related analytical methods. In this Review, some of these new developments are introduced from the materials science perspective.