Graphene oxide as an electrophile for carbon nucleophiles

The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound "molecular lynchpins" can be chemically modified to increase the solubility of the graphene derivative in either organic or aqueous environments...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-08, Vol.47 (31), p.8790-8792
Hauptverfasser: Collins, William R, Schmois, Ezequiel, Swager, Timothy M
Format: Artikel
Sprache:eng
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Zusammenfassung:The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound "molecular lynchpins" can be chemically modified to increase the solubility of the graphene derivative in either organic or aqueous environments.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc12829a