Dimerization of a Metal Complex through Thermally Induced Single-Crystal-to-Single-Crystal Transformation or Mechanochemical Reaction

Dimerization of a Metal Complex through Thermally Induced Single-Crystal-to-Single-Crystal Transformation or Mechanochemical Reaction

Come together: Monomers of copper carboxylate complex 1 (see picture, Cu blue‐green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H‐bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single‐crystal‐to‐single‐crystal transformation or by...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-07, Vol.50 (31), p.7061-7064
Hauptverfasser: Sun, Jie, Dai, Fangna, Yuan, Wenbing, Bi, Wenhua, Zhao, Xiaoliang, Sun, Wenming, Sun, Daofeng
Format: Artikel
Sprache:eng
Schlagworte:
coordination modes
copper
dimerization
mechanochemical reactions
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Zusammenfassung:Come together: Monomers of copper carboxylate complex 1 (see picture, Cu blue‐green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H‐bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single‐crystal‐to‐single‐crystal transformation or by mechanochemical reaction.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201101277