cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κC,S:S)tetrakis[chloridocobalt(III)]

cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κC,S:S)tetrakis[chloridocobalt(III)]

In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H⋯Cl hydrogen bonds. In the crystal, inter-molecular C-H⋯Cl and C-H⋯S hy...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-05, Vol.67 (Pt 5), p.m576-m577
Hauptverfasser: Awan, Shafique Ahmad, Tahir, M Nawaz, Muhammad, Iram Khushi, Ahmad, Saeed, Tariq, Muhammad Ilyas
Format: Artikel
Sprache:eng
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Zusammenfassung:In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H⋯Cl hydrogen bonds. In the crystal, inter-molecular C-H⋯Cl and C-H⋯S hydrogen bonds with R(2) (2)(8), R(4) (2)(8) and R(2) (2)(6) ring motifs generate a polymeric network.
ISSN:1600-5368
DOI:10.1107/S1600536811013067