Hydrogen-Bond-Directed 2-D Sheet Assemblies of Sulfamide Derivatives: Formation of Giant Vesicles with Patchwork-Like Surface Pattern
Sulfamide derivatives showed high ability to form hydrogen-bond-directed two-dimensional (2-D) sheet assemblies of nanometer thickness. Further, fine-tuning of the side chain structures and preparation conditions allowed for the formation of micrometer-sized giant vesicles of 4b in water by the simp...
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| Veröffentlicht in: | Langmuir 2011-07, Vol.27 (14), p.8950-8955 |
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| creator | Kabashima, Shin-ichiro Tanaka, Sachiko Kageyama, Motohiro Yoshikawa, Isao Araki, Koji |
| description | Sulfamide derivatives showed high ability to form hydrogen-bond-directed two-dimensional (2-D) sheet assemblies of nanometer thickness. Further, fine-tuning of the side chain structures and preparation conditions allowed for the formation of micrometer-sized giant vesicles of 4b in water by the simple injection method. IR and XRD studies indicated that 4b having tetradecyl and oxyethylene-terminated alkyl side chains formed hydrogen-bond-directed 2-D nanosheet pairs. SEM, AFM, and TEM observation of the dried vesicles revealed that the vesicle membrane was composed of several lamellar-stacked layers of 2-D nanosheets and showed a characteristic patchwork-like pattern on the surface. |
| doi_str_mv | 10.1021/la200985m |
| format | Article |
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| subjects | Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Hydrogen Bonding Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites Membranes Models, Molecular Molecular Conformation Nanostructures - chemistry Sulfuric Acids - chemistry Surface Properties Water - chemistry |
| title | Hydrogen-Bond-Directed 2-D Sheet Assemblies of Sulfamide Derivatives: Formation of Giant Vesicles with Patchwork-Like Surface Pattern |
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