More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB(2)N(2)(-) skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB(2)N(2)(-) ligand can be more electron-ric...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (29), p.8391-8393
Hauptverfasser: Ly, Hanh V, Moilanen, Jani, Tuononen, Heikki M, Parvez, Masood, Roesler, Roland
Format: Artikel
Sprache:eng
Schlagworte:
Analogs
Computation
Ferrocenes
Iron
Ligands
Metal ions
Ruthenium
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Zusammenfassung:Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB(2)N(2)(-) skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB(2)N(2)(-) ligand can be more electron-rich than its organic counterpart.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc12281a