Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand

The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.

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Bibliographische Detailangaben
Veröffentlicht in:	Analyst (London) 2011-08, Vol.136 (15), p.3069-3072
Hauptverfasser:	ZAMMIT, Elizabeth M, BARNETT, Neil W, HENDERSON, Luke C, DYSON, Gail A, MING ZHOU, FRANCIS, Paul S
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical chemistry Cerium - chemistry Chemical and thermal methods Chemistry Coordination Complexes - chemistry Exact sciences and technology Halogenation Iridium - chemistry Luminescence Luminescent Measurements - methods Phenanthrolines - chemistry Pyridines - chemistry Spectrometric and optical methods
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Beschreibung
Zusammenfassung:	The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.
ISSN:	0003-2654 1364-5528
DOI:	10.1039/c1an15315c