(Aqua-2κO)bis(2,2′-bipyridine-1κ2N,N′){μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)-1:2κ2O,O′:κ4O′′,N,N′,N′′}copper(II)nickel(II) perchlorate

(Aqua-2κO)bis(2,2′-bipyridine-1κ2N,N′){μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)-1:2κ2O,O′:κ4O′′,N,N′,N′′}copper(II)nickel(II) perchlorate

The title complex, [CuNi(C13H16N3O3)(C10H8N2)2(H2O)]ClO4, has a cis‐oxamide‐bridged heterobinuclear cation, with a Cu...Ni separation of 5.3297 (6) Å, counterbalanced by a disordered perchlorate anion. The CuII and NiII cations are located in square‐pyramidal and octahedral coordination environments...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2011-04, Vol.67 (4), p.m115-m118
Hauptverfasser: Yue, Xi-Teng, Nie, Jin-Ju, Li, Yan-Tuan, Wu, Zhi-Yong, Yan, Cui-Wei
Format: Artikel
Sprache:eng
Schlagworte:
Chemical compounds
Copper - chemistry
Crystal structure
Crystallography
Crystallography, X-Ray
Hydrogen Bonding
Hydrogen bonds
Ligands
Models, Molecular
Molecular Structure
Molecules
Nickel - chemistry
Organometallic Compounds - chemistry
Perchlorates
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Zusammenfassung:The title complex, [CuNi(C13H16N3O3)(C10H8N2)2(H2O)]ClO4, has a cis‐oxamide‐bridged heterobinuclear cation, with a Cu...Ni separation of 5.3297 (6) Å, counterbalanced by a disordered perchlorate anion. The CuII and NiII cations are located in square‐pyramidal and octahedral coordination environments, respectively. The complex molecules are assembled into a three‐dimensional supramolecular structure through hydrogen bonds and π–π stacking interactions. The influence of the two types of metal cation on the supramolecular structure is discussed.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270111008705