Time-dependent performance changes in LSCF-infiltrated SOFC cathodes: The role of nano-particle coarsening

Symmetric solid oxide cells with Gd doped ceria (GDC) electrolytes and La 0.6Sr 0.4Co 0.2Fe 0.8O 3 – δ (LSCF)-infiltrated-GDC cathodes were maintained in air with no current at temperatures from 650 to 850 °C. Comparison of SEM images before and after aging showed inhomogeneous coarsening of LSCF nano-particles in the cathodes. The polarization resistance, measured periodically at 600 °C using electrochemical impedance spectroscopy, increased at a higher rate with increasing aging temperature. The resistance variation was fit using a model that relates resistance to time-dependent LSCF surface area, based on surface diffusion limited coarsening. Good agreement with the experimental data is obtained for a limited range of fitting parameters. The model predicts that the cathode resistance should increase from ~ 0.2 to 0.28–0.35 Ω cm 2, if maintained at the operating temperature of 600 °C for 40,000 h. ► Accelerated testing method developed for infiltrated LSCF-GDC cathodes. ► Power law models for coarsening fit cathode performance variation. ► Prediction of cathode performance out to 40,000 h shows 40–70% degradation. ► SEM images indicate loss of LSCF surface area at high coarsening temperatures.