Remarkable Metal-Complexed Phosphorus Analogues of the Cyclopropenylcarbene–Cyclobutadiene Rearrangement

Remarkable Metal-Complexed Phosphorus Analogues of the Cyclopropenylcarbene–Cyclobutadiene Rearrangement

In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule...

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Veröffentlicht in:Journal of the American Chemical Society 2011-06, Vol.133 (25), p.9704-9707
Hauptverfasser: Lyaskovskyy, Volodymyr, Elders, Niels, Ehlers, Andreas W, Lutz, Martin, Slootweg, J. Chris, Lammertsma, Koop
Format: Artikel
Sprache:eng
Schlagworte:
Butadienes
Coordination Complexes - chemistry
Cyclobutanes
Cyclopropanes
Methane - analogs & derivatives
Organic Chemistry Phenomena
Phosphines - chemistry
Phosphorus - chemistry
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Zusammenfassung:In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja203083c