Comparison of advanced oxidation processes for the removal of natural organic matter

This study examined the impact of UV, ozone (O 3), advanced oxidation processes (AOPs) including O 3/UV, H 2O 2/UV H 2O 2/O 3 in the change of molecular weight distribution (MWD) and disinfection by-product formation potential (DBPFP). Bench-scale experiments were conducted with surface river water and changes in the UV absorbance at 254 nm (UV 254), total organic carbon (TOC), trihalomethane and haloacetic acid formation potential (THMFP, HAAFP) and MWD of the raw and oxidized water were analyzed to evaluate treatment performance. Combination of O 3 and UV with H 2O 2 was found to result in more TOC and UV 254 reduction than the individual processes. The O 3/UV process was found to be the most effective AOP for NOM reduction, with TOC and UV 254 reduced by 31 and 88%, respectively. Application of O 3/UV and H 2O 2/UV treatments to the source waters organics with 190–1500 Da molecular weight resulted in the near complete alteration of the molecular weight of NOM from >900 Da to