Tunable Phosphorescent Emission through Energy Transfer within Multilayer Thin Films Based on a Carbazole‐Based Host and Ir(III)‐Complex Guest System

A new method to tune both phosphorescence emission intensity and spectroscopic colors based on the alternatively structured host/guest multilayer thin films prepared by the spin‐assisted LbL deposition is presented. Their emission characteristics are demonstrated with pairs of positively charged Ir‐PEI complexes as guests and negatively charged CBZ‐PAA as hosts. The phosphorescent emission of Ir‐PEI complexes is enhanced by the energy transfer from the host to the guest and, additionally, this energy transfer can be finely tuned by the insertion of spacer layers between the phosphorescent donor and acceptor layers to vary the emission intensity as well as to render different emission colors. Tunable phosphorescent emission properties such as intensity and color are realized by control of energy transfer between different colored Ir(III)‐complexes and a carbazole‐based host material in multilayer thin films prepared by the spin‐assisted layer‐by‐layer method. The fine tuning of emission properties is achieved by adding a non‐emitting spacer layer between the Ir(III)‐complex and host material of nanometer range.